Dr. Salgado-Mendoza, Pablo

The present study reports the synthesis of Fe2O3 nanoparticles on Pinus radiata sawdust (Fe2O3@PS) using a Eucalyptus globulus leaf extract. The morphology and structure of Fe2O3@PS were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and UV–Vis diffuse reflectance. The adsorption capacity of the system was evaluated by testing its ability to remove the Rhodamine B (RhB) dye. The optimization of the system was carried out using the Plackett–Burman design (PBD) and the response surface methodology (steepest ascent and the Box–Behnken design), which provided information on the main parameters affecting the adsorption process. The PBD results showed that the most important parameters for the removal of RhB using Fe2O3@PS were the removal time, the RhB concentration, and the initial pH of the system. The reusability of Fe2O3@PS under optimal conditions was tested and it was found to maintain its efficiency after five cycles of use. The efficiency and rate of RhB removal observed at pH values near 7.0 were found to be predominantly influenced by electrostatic interactions. In contrast, the analyses conducted at pH values near 8.3 exhibited reduced influence from electrostatic attractions, with π–π interactions and hydrogen bonds emerging as dominant forces. At pH values exceeding 8.3, all potential interactions between RhB and Fe2O3@PS exhibited diminished strength. This research provides valuable information on the formation of eco-friendly nanoparticles immobilized on a forest residue such as sawdust, which can effectively remove organic pollutants like RhB. This contributes to the valorization of resources and the search for solutions to water pollution.

In this work, the Fenton technology was applied to decolorize methylene blue (MB) and to inactivate Escherichia coli K12, used as recalcitrant compound and bacteria models respectively, in order to provide an approach into single and combinative effects of the main process variables influencing the Fenton technology. First, Box–Behnken design (BBD) was applied to evaluate and optimize the individual and interactive effects of three process parameters, namely Fe2+ concentration (6.0 × 10−4, 8.0 × 10−4 and 1.0 × 10−3 mol/L), molar ratio between H2O2 and Fe2+ (1:1, 2:1 and 3:1) and pH (3.0, 4.0 and 5.0) for Fenton technology. The responses studied in these models were the degree of MB decolorization (D%MB), rate constant of MB decolorization (kappMB) and E. coli K12 inactivation in uLog units (IuLogEC). According to the results of analysis of variances all of the proposed models were adequate with a high regression coefficient (R2 from 0.9911 to 0.9994). BBD results suggest that [H2O2]/[Fe2+] values had a significant effect only on D%MB response, [Fe2+] had a significant effect on all the responses, whereas pH had a significant effect on D%MB and IuLogEC. The optimum conditions obtained from response surface methodology for D%MB ([H2O2]/[Fe2+] = 2.9, [Fe2+] = 1.0 × 10−3 mol/L and pH = 3.2), kappMB ([H2O2]/[Fe2+] = 1.7, [Fe2+] = 1.0 × 10−3 mol/L and PH = 3.7) and IuLogEC ([H2O2]/[Fe2+] = 2.9, [Fe2+] = 7.6 × 10−4 mol/L and pH= 3.2) were in good agreement with the values predicted by the model.