Dra. Yéber-Ortiz, María

Electrocoagulation of landfill leachate has been widely investigated, however, only few reports include the reuse of the treated water. In this work, treated leachate is evaluated as irrigation water. The main obstacle is the high Sodium Absorption Ratio. Reducing this indicator involves decreasing Na+ and increasing Mg2+ or Ca2+. Sodium concentration reduction is difficult by electrochemical methods (E0 = −2.71 V); Ca2+ increasing is not feasible as it precipitates. Hence, the use of different Al-Mg anodes was tested tending to increase Mg2+ concentration in the treated water The alloy 88%wtAl-12%wtMg was able to remove 52.9% of COD, 98.1% of turbidity, 97.9% of color, obtaining a SAR of 8.2 meq·L−1, total hardness (TH) of 64.2 meq·L−1 and a soluble sodium percentage (SSP) of 75.8 meq·L−1. This was achieved by working at a current density of 15 mA cm−2, a treatment time of 15 min and a pH 5.0. The phytotoxicity of the treated leachate was evaluated by the germination index using Lactuca Sativa L., reaching a value of 83.2%, which is considered excellent for irrigation water. During growth, 3–4 primary leaves were observed in seedings after 21 days, similar to when potable water was used. The results demonstrate that electrocoagulation is an adequate treatment technique for the reuse of landfill leachate if appropriated materials are used as anodes working in well selected operational variables.

The possibility of using electrocoagulation for efficient removal of pollutants in the industrial liquid waste of a textile industry was studied. The performance of the process was evaluated through the analysis of color, turbidity, and chemical oxygen demand (COD). The analysis was first done with the wastewater coming from the process of dyeing linen, which is the most polluting of all effluents that reach the residual effluent pool (REP). For the analysis, the MODDE 7.0 software was used to construct a statistical model. With the results obtained from this model and the experimental measurements, response surfaces were obtained. These response surfaces predicted the behavior of electrocoagulation for different values of the studied variables (pH, current density, and treatment time). Based on the obtained results, the wastewater coming from the REP was treated using the optimum values for the operational variables. After the treatment it was possible to remove 86% color, 82% turbidity, and 59% COD. It was demonstrated that reusing the treated water in the process of wool dyeing does not have a negative effect on the quality of the dyed fabric. Thus, it is possible to implement the process in the textile industry to reduce the consumption of water.