Dr. Valdes-Morales, Hector

Ethylene stimulates ripening and senescence by promoting chlorophyll loss, red pigment synthesis, and softening of tomatoes and diminishes their shelf-life. The aim of this work was to study the performance of a novel copper- and zinc-based ethylene scavenger supported by ion-exchange on a naturally occurring zeolite by analyzing its ethylene adsorption capacity and the influence of ethylene scavenging on quality attributes during the postharvest life of tomatoes. The influence of copper- and zinc-modified zeolites on ethylene and carbon dioxide concentrations and postharvest quality of tomatoes was compared with unmodified zeolite. Interactions among ethylene molecules and zeolite surface were studied by diffuse reflectance infrared Fourier transform spectroscopy in operando mode. The percentage of ethylene removal after eight days of storage was 57% and 37% for the modified zeolite and pristine zeolite, respectively. The major ethylene increase appeared at 9.5 days for the modified zeolite treatment. Additionally, modified zeolite delayed carbon dioxide formation by six days. Zeolite modified with copper and zinc cations favors ethylene removal and delays tomato fruit ripening. However, the single use of unmodified zeolite should be reconsidered due to its ripening promoting effects in tomatoes at high moisture storage conditions, as water molecules block active sites for ethylene adsorption.

Ethylene is a plant growth regulator that induces accelerated softening and ripening of fruits during transport and storage. Among the most applied methods for ethylene control, adsorption appears as a cheap and efficient technique. In this work, the effect of the incorporation of transition metals into natural Chilean zeolite on ethylene adsorption is investigated. Natural zeolite mainly composed of clinoptilotite and mordenite is modified using copper and zinc nitrate solutions and calcined under oxygen flow at 623 K, generating different transition metal modified zeolites. Parent and modified zeolites were characterised by X-ray diffraction, X-ray fluorescence spectroscopy and nitrogen adsorption. Zeolite surface modifications were assessed by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). Experimental results reveal the incorporation of Cu2+ and Zn(2+ )as new compensating cations into the zeolite framework. Ethylene adsorption isotherms show an enhancement on the adsorption capacity of Cu-exchanged zeolite. This result is not only associated to the higher micropore surface area of this sample, but also to the higher affinity of ethylene molecules to copper cations incorporated on this zeolite. DRIFTS operando experiments of ethylene adsorption in the absence and in the presence of moisture reveal a competitive mechanism of water and ethylene molecules toward hydroxyl sites. Si-OH-Al and Si-OH sites are rapidly occupied with water, reducing the adsorption of ethylene.